Concept:The IUPAC name is decided by numbering the benzene ring so that the substituents receive the lowest possible set of locants.
Explanation:The benzene ring carries three substituents: chloro
−Cl, methyl
−CH3​, and nitro
−NO2​.
Number the ring to obtain the smallest locant set, which is
{1,2,4}.
Arrange the substituents alphabetically: chloro, methyl, nitro.
So the locants are assigned as
1-chloro,
4-methyl, and
2-nitro.
Hence, the correct IUPAC name is 1-chloro-4-methyl-2-nitrobenzene.
Option D is a common name, not the systematic IUPAC name.
Answer:B. 1-Chloro-4-methyl-2-nitrobenzene