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Question : 7
Total: 60
Which of the following statements about the reaction given below are correct?
MnO 2 + 4 HCl → MnCl 2 + 2 H 2 O + Cl 2
(i)HCl is oxidized to Cl 2
(ii)MnO 2 is reduced to MnCl 2
(iii)MnCl 2 acts as an oxidizing agent
(iv)HCl acts as on oxidizing agent
(i)
(ii)
(iii)
(iv)
Solution:
In the given reaction,
MnO 2 + 4 HCl → MnCl 2 + 2 H 2 O + Cl 2
HCl is getting oxidized to Cl 2 and MnO 2 is reduced to MnCl 2 . This can be explained as follows:
2 e +
→
2
Mn is going from +4 oxidation state to +2 oxidation thus clearly Mn is gaining electrons here MnO 2 is reduced to MnCl 2
2
→
+ 2 e −
HenceCl of HCl is in -1 oxidation state and after losing its one electron it goes to 0 (elementary form) oxidation state, hence here HCl is oxidised to Cl 2 .
Here,
Hence
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