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Question : 11
Total: 11
(A) (i) It is observed that covalent compounds are had conductors of electricity. Give reason.
(ii) Carbon can neither formC 4 cation nor C 4 anion. Why?
(iii) Draw electron dot structure of Ethanol.
(iv) Identify hetero atom(s) in the following compounds.
(a)CH 3 CH 2 −
− CH 3
(b)CH 3 CH 2 Cl
(B) (i) What are soaps? Explain the mechanism of cleansing action of soap with the help of a labelled diagram.
(ii) Detergents are better than soaps. Justify.
(ii) Carbon can neither form
(iii) Draw electron dot structure of Ethanol.
(iv) Identify hetero atom(s) in the following compounds.
(a)
(b)
(B) (i) What are soaps? Explain the mechanism of cleansing action of soap with the help of a labelled diagram.
(ii) Detergents are better than soaps. Justify.
Solution:
(A) (i) The bonds which are formed by the sharing of an electron pair between two atoms are known as covalent bonds. Since the electrons are shared between atoms and no charged particles are formed, such covalent compounds are generally poor conductors of electricity.
(ii) In the case of carbon, it has four electrons in its outermost shell and needs to gain or lose four electrons to attain noble gas configuration. If it were to gain or lose electrons:
1. It could gain four electrons formingC 4 − anion. But it would be difficult for the nucleus with six protons to hold on to ten electrons, that is, four extra electrons.
2. It could lose four electrons formingC 4 + cation. But it would require a large amount of energy to remove four electrons leaving behind a carbon cation with six protons in its nucleus holding on to just two electrons.
(iii) Electron dot structure of ethanol.
H :
:
:
: H (iv) (a) Oxygen is heteroatom.
(b) Chlorine is heteroatom.
OR
(B) (i) Soaps are sodium or potassium salts of long-chain carboxylic acids.
Cleansing action of soaps:
Soaps are molecules in which the two ends have differing properties, one is hydrophilic, that is, it interacts with water, while the other end is hydrophobic, that is, it interacts with hydrocarbons. When soap is at the surface of water, the hydrophobic 'tail' of soap will not be soluble in water and the soap will align along the surface of water with the ionic end in water and the hydrocarbon 'tail' protruding out of water. Inside water these molecules have a unique orientation that keeps the hydrocarbon portion out of the water. Thus, clusters of molecules in which the hydrophobic tails are in the interior of the cluster and the ionic ends are on the surface of the cluster. This formation is called a micelle. Soap in the form of a micelle is able to clean, since the oily dirt will be collected in the centre of the micelle. The micelles stay in solution as a colloid and will not come together to precipitate because of ion-ion repulsion. Thus, the dirt suspended in the micelles is also easily rinsed away. The soap micelles are large enough to scatter light. Hence a soap solution appears cloudy.
(ii) In the case of carbon, it has four electrons in its outermost shell and needs to gain or lose four electrons to attain noble gas configuration. If it were to gain or lose electrons:
1. It could gain four electrons forming
2. It could lose four electrons forming
(iii) Electron dot structure of ethanol.
(b) Chlorine is heteroatom.
OR
(B) (i) Soaps are sodium or potassium salts of long-chain carboxylic acids.
Cleansing action of soaps:
Soaps are molecules in which the two ends have differing properties, one is hydrophilic, that is, it interacts with water, while the other end is hydrophobic, that is, it interacts with hydrocarbons. When soap is at the surface of water, the hydrophobic 'tail' of soap will not be soluble in water and the soap will align along the surface of water with the ionic end in water and the hydrocarbon 'tail' protruding out of water. Inside water these molecules have a unique orientation that keeps the hydrocarbon portion out of the water. Thus, clusters of molecules in which the hydrophobic tails are in the interior of the cluster and the ionic ends are on the surface of the cluster. This formation is called a micelle. Soap in the form of a micelle is able to clean, since the oily dirt will be collected in the centre of the micelle. The micelles stay in solution as a colloid and will not come together to precipitate because of ion-ion repulsion. Thus, the dirt suspended in the micelles is also easily rinsed away. The soap micelles are large enough to scatter light. Hence a soap solution appears cloudy.
(ii) Detergents are generally sodium salts of sulphonic acids or ammonium salts with chlorides or bromides ions, etc. Both have long hydrocarbon chain. The charged ends of these compounds do not form insoluble precipitates with the calcium and magnesium ions in hard water. Thus, they remain effective in hard water. Detergents are usually used to make shampoos and products for cleaning clothes.
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