CBSE Class 12 Chemistry 2013 Solved Paper

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Question : 20
Total: 30
Determine the osmotic pressure of a solution prepared by dissolving 2.5×102g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R=0.0821L1atmK1mol1., Molar mass of K2SO4 =174gmol1)
Solution:  
Reaction is:
K2SO42K++SO42
No. of produced ions =3
π=iCRT
π=
3×0.025×0.0821×0.5×298
174

=
0.917
174

=0.00527
=5.27×103atm
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