CBSE Class 12 Chemistry 2014 Delhi Set 1 Solved Paper

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Question : 11
Total: 30
Calculate the mass of compound (molar mass = 256gmol1 ) to be dissolved in 75g of benzene to lower its freezing point by 0.48K(Kf=5.12Kkg. mol1 ).
Solution:  
Let Xg of the compound is to be dissolved. Number of moles of compound,
n=
molar mass
given mass
=
256
W

Mass of Benzene =75g=0.075Kg
Molality =
moles of solute
mass of solvent in kg

=
W
256×0.075
=
W
19.2

Freezing point depression ΔTf=0.48 K
Molar depression of freezing point constant =5.12 K kg mol
It is defined as the total number of molecules of reactants.
Tf=Kf0.48
=5.12 W=1.8 g
Hence, 1.8 g solute has been dissolved.
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