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Question : 11
Total: 30
Calculate the mass of compound (molar mass = 256 g mol − 1 ) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K ( K f = 5.12 K kg . mol − 1 ).
Solution:
Let X g of the compound is to be dissolved. Number of moles of compound,
n =
=
Mass of Benzene= 75 g = 0.075 K g
Molality=
=
=
Freezing point depressionΔ T f = 0.48 K
Molar depression of freezing point constant= 5.12 K k g ∕ m o l
It is defined as the total number of molecules of reactants.
⇒ T f = K f 0.48
= 5.12 W = 1.8 g
Hence,1.8 g solute has been dissolved.
Mass of Benzene
Molality
Freezing point depression
Molar depression of freezing point constant
It is defined as the total number of molecules of reactants.
Hence,
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