CBSE Class 12 Chemistry 2014 Delhi Set 1 Solved Paper

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Question : 27
Total: 30
Give the structures of A,B and C in the following reactions:
(i) CH3Br
KCN
A
LiAlH4
B
HNO2
C

(ii) CH3COOH
NH3
A
Br2+KOH
B
CHCl3+NaOH
C

OR
How will you convert the following?
(i) Nitrobenzene into aniline.
(ii) Ethanoic acid into methanamine.
(iii) Aniline into N-phenylethanamide.
(Write the chemical equations involved.)
Solution:  
(i) CH3Br
KCN
CH3CN
LiAlH4
CH3CH2NH2
HNO2
CH3CH2OH

(ii) CH3COOH
NH3
CH3CONH2
Br2+KOH
CH3NH2
CHCl3+NaOH
CH3NC

OR
(i) Nitrobenzene into aniline
(ii) Ethanoic acid to methenamine
CH3COOH
NH3
CH3
CONH2
Br2+KOH
CH3
NH2

(iii) Aniline into N-phenylethaneamide
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