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Question : 19
Total: 26
(a) How would you account for the following:
(i) Actinoid contraction is greater than lanthanoid contraction.
(ii) Transition metals form coloured compounds.
(b) Complete the following equation:
2 MnO 4 − + 6 H + + 5 NO 2 − ─ ─ ─ ─ ▸
(i) Actinoid contraction is greater than lanthanoid contraction.
(ii) Transition metals form coloured compounds.
(b) Complete the following equation:
Solution:
(a) (i) 5 f orbital electrons have poor shielding effect than 4 f orbital electrons.
(ii) Due tod - d transition or the energy of excitation of an electron from lower d orbital to higher d -orbital lies in the visible region and presence of unpaired electrons in the d -orbital.
(b)2 MnO 4 − + 6 H + + 5 NO 2 − ─ ─ ─ ─ ▸ 2 Mn 2 + + 3 H 2 O + 5 NO 3 −
(ii) Due to
(b)
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