CBSE Class 12 Chemistry 2015 Solved Paper

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Question : 26
Total: 26
An aromatic compound ' A ' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions:

OR
(a) Write the structures of main products when aniline reacts with the following reagents:
(i) Br2 /water
(ii) HCl
(iii) (CH3CO)2O pyridine
(b) Arrange the following in the increasing order of their boiling point:
C2H5NH2,C2H5OH,(CH3)3N
(c) Give a simple chemical test to distinguish between the following pair of compounds:
(CH3)2NH and (CH3)3N
Solution:  
OR
(b) (CH3)3N<C2H5NH2<C2H5OH
(c) By Hinsberg test of secondary amines (CH3)2NH shows ppt. formation which is insoluble KOH while in tertiary amines, (CH3)3N do not react with benzene sulphonyl choride.
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