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Question : 26
Total: 26
An aromatic compound ' A ' of molecular formula C 7 H 7 ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions:
OR
(a) Write the structures of main products when aniline reacts with the following reagents:
(i)Br 2 /water
(ii)HCl
(iii)( CH 3 CO ) 2 O ∕ pyridine
(b) Arrange the following in the increasing order of their boiling point:
C 2 H 5 NH 2 , C 2 H 5 OH , ( CH 3 ) 3 N
(c) Give a simple chemical test to distinguish between the following pair of compounds:
( CH 3 ) 2 NH and ( CH 3 ) 3 N
OR
(a) Write the structures of main products when aniline reacts with the following reagents:
(i)
(ii)
(iii)
(b) Arrange the following in the increasing order of their boiling point:
(c) Give a simple chemical test to distinguish between the following pair of compounds:
Solution:
OR
(b)
(c) By Hinsberg test of secondary amines
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