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Read the given passage and answer the questions that follow:
The halogens have the smallest atomic radii in their respective periods. The atomic radius of fluorine is extremely small. All halogens exhibit -1 oxidation state. They are strong oxidising agents and have maximum negative electron gain enthalpy. Among halogens, fluorine shows anomalous behaviour in many properties. For example electronegativity and ionisation enthalpy are higher for fluorine than expected whereas bond dissociation enthalpy, m.p. and b.p. and electron gain enthalpy are quite lower than expected. Halogens react with hydrogen to give hydrogen halides( HX ) and combine amongst themselves to form a number of compounds of the type X X ′ , X X 3 ′ , X X 5 ′ and X X 7 ′ called inter-halogens.
SECTION -A
Read the given passage and answer the questions that follow:
The halogens have the smallest atomic radii in their respective periods. The atomic radius of fluorine is extremely small. All halogens exhibit -1 oxidation state. They are strong oxidising agents and have maximum negative electron gain enthalpy. Among halogens, fluorine shows anomalous behaviour in many properties. For example electronegativity and ionisation enthalpy are higher for fluorine than expected whereas bond dissociation enthalpy, m.p. and b.p. and electron gain enthalpy are quite lower than expected. Halogens react with hydrogen to give hydrogen halides
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Question : 2
Total: 37
Why fluorine shows anomalous behaviour as compared to other halogens?
Solution:
(i) It has smallest in size.
(ii) Very high electronegativity.
(iii) Absence ofd -orbitals.
(iv) dissociation enthalpy in molecular form is least .
(ii) Very high electronegativity.
(iii) Absence of
(iv) dissociation enthalpy in molecular form is least .
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