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Question : 29
Total: 37
Calculate the de Broglie wavelength associated with the electron revolving in the first excited state of hydrogen atom. The ground state energy of hydrogen atom is − 13.6 eV .
Solution:
The energy of the n th state of Hydrogen atom
En =
eV
For ground state,n = 1
When atom is in first excited state,n = 2
∴ E =
= − 3.4 eV
Now, the de Broglie wavelength associated with an electron is
λ =
h = Planck's constant
p = Momentum of electron
m = Mass of electron
p = √ 2 m E
∴ λ =
Or λ =
Or, λ =
∴ λ =
= 0.66 × 10 − 9
= 6.6 A 0
For ground state,
When atom is in first excited state,
Now, the de Broglie wavelength associated with an electron is
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