NCERT Class XI Chemistry Classification of Elements and Periodicity in Properties Solutions

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Question : 24
Total: 40
Describe the theory associated with the radius of an atom as it
(a) gains an electron
(b) loses an electron.
Solution:  
The distance between the nucleus and the outermost shell of an ion is known as ionic radius.
(a) The gain of an electron leads to the formation of an anion. The radius of the anion is larger than the atomic radius of its parent atom because the addition of one or more electrons would result in increased repulsion among the electrons and a decrease in effective nuclear charge which acts on more electrons so, each electron is held less tightly and thereby the electron cloud expands.
(b) The removal of an electron from an atom results in the formation of a cation.
A cation is smaller than its parent atom because it has fewer electrons while its nuclear charge remains the same and since it is now acting on lesser number of electrons and pulls them closer, the ion is smaller.
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