NCERT Class XI Chemistry Classification of Elements and Periodicity in Properties Solutions

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Question : 28
Total: 40
The increasing order of reactivity among group 1 elements is Li < Na < K < Rb < Cs whereas that among group 17 elements is F > Cl > Br > I. Explain.
Solution:  
The trend Li < Na < K < Rb < Cs is observed for chemical reactivity because upon descending the group the ionization energy of alkali metals decreases i.e., it is easy for them to lose an electron from their valence shell and attain the nearest stable noble gas configuration.
The trend F > Cl > Br > I is observed for chemical reactivity in halogens because the standard reduction potential decreases as we descend the group. F being the most electronegative readily accepts an e– to complete its octet and hence the trend.
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