NCERT Class XI Chemistry Hydrogen Solutions

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Question : 15
Total: 36
Saline hydrides are known to react with water violently producing fire. Can CO2, a well-known fire extinguisher, be used in this case? Explain.
Solution:  
When saline hydrides react with water, the reaction is highly exothermic, the evolved hydrogen catches fire. e.g.,
NaH(s)+H2O(aq)NaOH(aq)+H2(g) ↑ + heat
CO2 cannot be used in this case because it will react with hot metal hydride.
NaH + CO2 → HCOONa
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