NCERT Class XI Chemistry Hydrogen Solutions

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Question : 23
Total: 36
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
Solution:  
Hard water is made soft by a very common ion exchange resin method. In this the hard water is allowed to pass over a zeolite bed [zeolites are sodium aluminium silicates (Na2Al2Si2O8·xH2O)] during which the Na+ ions from zeolite are replaced by Ca2+ and Mg2+ ions.
Na2Z+Ca2+CaZ+2Na+
Na2Z+Mg2+MgZ+2Na+
When whole of the Na+ ions of the zeolite have been exchanged, the zeolite is regenerated by treating it with strong (or saturated) solution of NaCl.
MZ + 2NaCl → Na2Z+MCl2 (M = Mg, Ca)
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