NCERT Class XI Chemistry Hydrogen Solutions

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Question : 5
Total: 36
Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?
Solution:  
Dihydrogen is prepared by the electrolysis of water using platinum electrodes in the presence of a small amount of acid or alkali.
2H2O(l)
Electrolysis
→
acid∕base
2H2(g)+O2(g)
During electrolysis, the reactions that take place are :
H2O ⇌ H++OH−
At cathode :
H++e− → H
H + H → H2(g) ↑
At anode :
4OH− → 4OH+4e−
4OH → 2H2O(l)+O2(g)
The hydrogen prepared by this method is of very high purity.
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