NCERT Class XI Chemistry Redox Reactions Solutions

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Question : 28
Total: 30
Arrange the following metals in the order in which they displace each other from the solution of their salts. Al, Cu, Fe, Mg and Zn.
Solution:  
We know that, E°Al3+Al = –1.66 V, E°Cu2+Cu= + 0.34 V,
E°Fe2+Fe = – 0.44 V, E°Mg2+Mg = – 2.36 V and E°Zn2+Zn = – 0.76 V.
Since a metal with lower electrode potential is a stronger reducing agent, therefore, Mg can displace all the above metals from their aqueous solutions, Al can displace all metals except Mg from the aqueous solutions of their salts. Zn can displace all metals except Mg and Al from the aqueous solutions of their salts while Fe can displace only Cu from the aqueous solution of its salts. Thus, the order in which they can displace each other from the solution of their salts is Mg, Al, Zn, Fe, Cu.
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