NCERT Class XI Chemistry Structure of Atom Solutions
© examsnet.com
Question : 52
Total: 67
Following results are observed when sodium metal is irradiated with different wavelengths. Calculate (a) threshold wavelength and, (b) Planck’s constant.
Solution:
Let the threshold wavelength = λ 0 nm = λ 0 × 10 – 9 m then
h c (
−
) =
m v 2
Substituting the given three experiments,
(
−
) =
m ( 2.55 × 10 5 ) 2 ... (i)
(
−
) =
m ( 4.35 × 10 5 ) 2 ... (ii)
(
−
) =
m ( 2.55 × 10 5 ) 2 ... (iii)
Dividing equation (ii) by equation (i) we get,
×
= (
) 2 or
=
× (
) 2
or
=
×
or
= 2.62
orλ 0 – 450 = 2.62 λ 0 – 1310 or – 450 + 1310 = 2.62 λ 0 – λ 0
or 860 = 1.62λ 0 ⇒ λ 0 =
= 530.86 nm ≈ 531 nm
Putting this in equation (iii), we get
(
−
) =
( 9.1 × 10 − 31 ) ( 5.20 × 10 5 ) 2
h × 3 ×10 17 (
) =
× 27.04 × 10 10 × 9.1 × 10 − 31
⇒ h = 6.64 ×10 − 34 J s .
Substituting the given three experiments,
Dividing equation (ii) by equation (i) we get,
or
or
or 860 = 1.62
Putting this in equation (iii), we get
h × 3 ×
⇒ h = 6.64 ×
© examsnet.com
Go to Question: