NCERT Class XI Chemistry Structure of Atom Solutions

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Question : 56
Total: 67
Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
Solution:  
Radius of nth orbit of H-like particles =
0.529×n2
Z
Å
=
52.9×n2
Z
pm
Radius (r1) = 1.3225 nm = 1322.5 pm =
52.9n12
Z

Radius (r2) = 211.6 pm =
52.9n22
Z

r1
r2
=
1322.5
211.6
=
n12
n22
⇒ 6.25 =
n12
n22
= (
n1
n2
)
2
= 6.25 ⇒
n1
n2
= 6.25 = 2.5
n2 = 2, n1 = 5 thus, the transition is from 5th orbit to 2nd orbit. It belongs to Balmer series.
v
= 1.097 × 107(
1
22
1
52
)
= 1.097 × 107(
1
4
1
25
)
= 1.097 × 107×
21
100

λ =
1
v
=
100
1.097×21×107
m = 4.34 × 107m = 434 × 109m = 434 nm
Thus, it lies in the visible region.
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