NCERT Class XI Chemistry The p-Block Elements Solutions

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Question : 26
Total: 38
(a) Classify following oxides as neutral, acidic, basic or amphoteric:
CO, B2O3,SiO2,CO2 , Al2O3,PbO2,Tl2O3
(b) Write suitable chemical equations to show their nature.
Solution:  
(a) Neutral oxides : CO
Acidic oxides : B2O3,SiO2,CO2
Basic oxides : Tl2O3
Amphoteric oxides : Al2O3,PbO2
(b) (i) CO Neutral to litmus [Neutral]
(ii) B2O3 reacts with basic (metallic) oxides forming meta-borates.
B2O3+CuOCu(BO2)2 [Acidic]
(iii) SiO2+2NaOHNa2SiO3+H2O [Acidic]
(iv) CO2+2NaOHNa2CO3+H2O [Acidic]
(v) Tl2O3+3H2SO4Tl2(SO4)3+3H2O [Basic]
(vi) Al2O3+6HCl2AlCl3+3H2O [Amphoteric]
Al2O3+2NaOHNa2AlO2+H2O [Amphoteric]
(vii) PbO2+2NaOHNa2PbO3+H2O [Amphoteric]
PbO2+4HClPbCl2+Cl2+2H2O [Amphoteric]
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