NCERT Class XI Chemistry The p-Block Elements Solutions

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Question : 32
Total: 38
Give one method for industrial preparation and one for laboratory preparation of CO and CO2 each.
Solution:  
Preparation of CO :
Lab method : Pure CO is prepared by dehydration of formic acid or oxalic acid with concentrated H2SO4 at 373 K.
HCOOH
373K
conc.H2SO4
CO + H2O
Industrial method : CO is prepared by the passage of steam over hot coke. The mixture of CO and H2 thus, produced is known as water gas or synthesis gas.
C(s)+H2O(g)
4731273K
CO(g)+H2(g)
Watergas

When air is used instead of steam, a mixture of CO and N2 is produced, which is called producer gas.
2C(s)+O2(g)+N2(g)
1273K
2CO(g)+N2(g)
Producergas

Preparation of CO2 :
Lab method : In the laboratory it is conveniently prepared by the action of dilute HCl on calcium carbonate.
CaCO3(s)+2HCl(aq)CaCl2(aq)+CO2(g)+H2O(l)
Industrial method : When lime is manufactured by the calcination of limestone (CaCO3), carbon dioxide is obtained as a by product.
CaCO3CaO+CO2
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