NCERT Class XI Chemistry The s-Block Elements Solutions

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Question : 27
Total: 32
State as to why
(a) a solution of Na2CO3 is alkaline?
(b) alkali metals are prepared by electrolysis of their fused chlorides?
(c) sodium is found to be more useful than potassium?
Solution:  
(a) Sodium carbonate being a salt of strong base (NaOH) and weak acid (H2CO3) forms an alkaline solution upon hydrolysis.
Na2CO3+2H2O
2NaOH
Strongbase
+
H2CO3
Weakacid

(b) Alkali metals are prepared by the electrolysis of their fused chlorides as if aqueous solution of their salts are used for extraction by electrolytic method then hydrogen is discharged at cathode instead of an alkali metal as the discharge potentials of alkali metals are high.
(c) Sodium is relatively more abundant than potassium. At the same time, it is also less reactive and its reactions with other substances can be better controlled.
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