Thermodynamics

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Question : 5
Total: 10
In changing the state of a gas adiabatically from an equilibrium state A to another equilibrium state B, an amount of work equal to 22.3 J is done on the system. If the gas is taken from state A to B via a process in which the net heat absorbed by the system is 9.35 cal, how much is the net work done by the system in the latter case? (Take 1 cal = 4.19 J)
Solution:  
In first case, the state of the gas changes adiabatically from A to B.
Therefore, ΔQ=0,DW=22.3J
If ΔU is change in internal energy of the system then,
ΔQ=ΔU+ΔW
0=ΔU+ΔW
ΔU=ΔW=(22.3J)
=22.3J
In the second case, when the state A is taken to state B, the heat absorbed by the system
ΔQ=9.35cal
=9.35×4.2J=39.27J
=39.3J,Δ W=?
Applying first law of thermodynamics
ΔQ=ΔU+ΔW
ΔW=ΔUΔQ
=39.322.3=17.0 J
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