NCERT Class XII Chemistry
Chapter - Amines
Questions with Solutions

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Question : 16
Total: 22
(a) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N.
(b) Write IUPAC names of all the isomers.
(c) What type of isomerism is exhibited by different pairs of amines?
Solution:  
(a and b)
Primary amines :
(i)
CH3CH2CH2CH2NH2
Butanamine

(ii)
CH3CH2
C
|
NH3
H
CH3
Butan2amine

(iii)
CH3
CH3
|
C
|
CH3
NH2
2Methylpropan2amine

(iv)
CH3
CH3
|
C
H
CH2
NH2
2Methylpropan1amine

(v)
CH3CH2NHCH2CH3
NEthylethanamine

(vi)
CH3CH2CH2NHCH3
NMethylpropanamine

(vii)
CH3
CH3
|
C
H
NH
CH3
NMethylpropan2amine

Tertiary amine:
(viii)
CH3
CH3
|
N
CH2CH3
N,NDimethylethanamine

(c) Chain isomers : (i) & (iv), (ii) & (iii), (i) & (iii), (ii) & (iv)
Position isomers : (i) & (ii), (vi) & (vii)
Metamers : (v) & (vi), (v) & (vii)
Functional isomers: All primary amines are functional isomers of secondary and tertiary amines and vice versa.
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