NCERT Class XII Chemistry
Chapter - Chemical Kinetics
Questions with Solutions
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Question : 17
Total: 39
During nuclear explosion, one of the products is 90 Sr with half-life of 28.1 years. If 1 µg of 90 Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically ?
Solution:
As radioactive disintegration follows first order kinetics. Hence Decay constant of 90 Sr , ( λ ) =
=
= 2.466 × 10 − 2 y r − 1
To calculate the amount left after 10 years
Given, [ R 0 ] = 1 µ g ,
t = 10 years,
k = 2.466 × 10 − 2 y r − 1 , [ R ] = ?
Using formula,λ =
log
or2.466 × 10 − 2 = 2.303 10 log
or,
= − log [ R ]
or,log [ R ] = − 0.1071
or,[ R ] = Antilog ( − 0.1071 ) = 0.7814 µ g
To calculate the amount left after 60 years, t = 60 years,[ R 0 ] = 1 µg, [R] = ?
or,2.466 × 10 − 2 =
log
or,
= − log [ R ]
or,log [ R ] = − 0.6425
or,[ R ] = Antilog ( − 0.6425 ) = 0.2278 µ g
To calculate the amount left after 10 years
Given,
Using formula,
or
or,
or,
or,
To calculate the amount left after 60 years, t = 60 years,
or,
or,
or,
or,
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