NCERT Class XII Chemistry
Chapter - Chemical Kinetics
Questions with Solutions
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Question : 23
Total: 39
The rate constant for the decomposition of a hydrocarbon is 2.418 × 10 – 5 s – 1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor.
Solution:
Here, k = 2.418 × 10 − 5 s − 1 ,
E a = 179.9 k J m o l − 1 ,
T = 546 K , A = ?
According to Arrhenius equation,
log A = log k +
= log ( 2.418 × 10 − 5 ) +
= ( − 5 + 0.3834 ) + 17.2081
= 12.5924 s − 1
or,A = Antilog ( 12.5924 ) s − 1
= 3.912 × 10 12 s − 1
According to Arrhenius equation,
or,
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