NCERT Class XII Chemistry
Chapter - Chemical Kinetics
Questions with Solutions
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Question : 7
Total: 39
What is the effect of temperature on the rate constant of a reaction?
How can this temperature effect on rate constant be represented quantitatively?
How can this temperature effect on rate constant be represented quantitatively?
Solution:
The rate constant increases with increase in temperature and becomesalmost double for every 10° increase in temperature. Swedish chemist,Arrhenius derived a quantitative relation between rate of reaction andtemperature. According to Arrhenius,
k = A e −
or,log k = log A − E a R T
or,log
=
[
−
]
wherek 1 = rate constant at temperature T 1 ,
k 2 = rate constant at temperature T 2 ,
E a = energy of activation, R = universal gas constant.
or,
or,
where
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