NCERT Class XII Chemistry
Chapter - Electrochemistry
Questions with Solutions

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Question : 26
Total: 32
Suggest a way to determine the Λ0m value of water.
Solution:  
Water is a weak electrolyte. Its Λ0m value can be determined with thehelp of Kohlrausch’s law.
Λm0( HCl)=Λm0 (H+ )+Λm0 ( Cl).......(i)
Λm0( NaOH)=Λm0( Na+ )+Λm0 ( OH)........ (ii)
Λm0( NaCl)=Λm0 ( Na+)+Λm0 (Cl ).......(iii)
Adding (i) and (ii) and subtracting (iii) we get
Λm0( H2O )=Λm0 ( H+ )+Λm0 ( OH)
=Λm0( HCl)+Λm0( NaOH)Λm0( NaCl)
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