NCERT Class XII Chemistry
Chapter - Solutions
Questions with Solutions

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Question : 4
Total: 53
Concentrated nitric acid used in the laboratory is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of the acid if the density of the solution is 1.504 g mL 1 ?
Solution:  
Let mass of solution = 100 g
Then mass of nitric acid = 68 g
Molar mass of HNO3=63g mol1
Number of moles of HNO3=
68
63
=1.079
mole
Density of solution = 1.504 g mL1
∴ Volume of solution =
100g
1.504gmL1
= 66.5 mL = 0.0665 L
Molarity of the solution =
Number of moles of the solute
Volume of solution in L
=
1.079
0.0665
= 16.23 M
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