NCERT Class XII Chemistry
Chapter - The d- and f-Block Elements
Questions with Solutions

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Question : 18
Total: 49
Predict which of the following will be coloured in aqueous solution?
Ti3+,V3+,Cu+,Sc3+,Mn2+,Fe3+ and Co2+. Give reasons for each.
Solution:  
The configuration of the given metal ions can be given as
Ti3+–‌3d14s0‌ 1 unpaired electron
V3+–‌3d24s0‌ 2 unpaired electrons
Cu+–‌3d104s0‌ No unpaired electron
Sc3+–‌3d04s0‌ No unpaired electron
Mn2+–‌3d54s0‌ 5 unpaired electrons
Fe3+–‌3d54s0‌ 5 unpaired electrons
Co2+–‌3d74s0‌ 3 unpaired electrons
Out of these only Cu+and Sc3+ are colourless. All other ions are coloureddue to presence of unpaired electrons.
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