NCERT Class XII Chemistry
Chapter - The d- and f-Block Elements
Questions with Solutions

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Question : 26
Total: 49
Indicate the steps in the preparation of
(i) K2Cr2O7 from chromite ore
(ii) KMnO4 from pyrolusite ore.
Solution:  
(i) 4FeCr2O4+8Na2CO3+7O28Na2CrO4+2Fe2O3+8CO2
2Na2CrO4+2H+Na2Cr2O7+2Na++H2O
Na2Cr2O7+2KClK2Cr2O7+2NaCl
(ii)2MnO2+4KOH+O2
2
K2
M
n
O4
+2H2O
3MnO42+4H+2MnO4+MnO2+2H2O
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