NCERT Class XII Chemistry
Chapter - The Solid State
Questions with Solutions

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Question : 24
Total: 50
Aluminium crystallises in a cubic close packed structure. Its metallic radius is 125 pm.
(i) What is the length of the side of the unit cell?
(ii) How many unit cells are there in 1.00 cm3 of aluminium?
Solution:  
Given r=125 pm,a=?, structure =ccp( fcc)
(i)Forccp(fcc),a=22r
=2×1.414×125pm=354 pm
=2×1.414×125 pm=354pm(ii)
Volumeofoneunitcell=a3
= (354×1010 cm)3=4.44×1023cm3
Number of unit cells in 1 cm3=
1cm3
4.44×1023cm3

=2.25×1022
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