CO2 (g) Phase transition, ΔH = +ve and ΔS = + ve (B) CaCO3 (s)
Δ
→
CaO(s)+CO2(g) No phase transition, ΔH= +ve and ΔS = +ve (C) 2H → H2(g) Two particles give one gaseous particle, so ΔS = −ve (D) P(white,solid)
Δ
→
P(red,solid) This is an allotropic change. ΔH is positive, as white phosphorus converts to red phosphorus on heating. ΔS is negative, as red phosphorus is a polymeric solid, less reactive than white phosphorous.