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JEE Advanced 2021 Paper 2

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A sample (5.6 g)(5.6\,\mathrm{g}) containing iron is completely dissolved in cold dilute HCl\mathrm{HCl} to prepare a 250 mL250\,\mathrm{mL} of solution. Titration of 25.0 mL25.0\,\mathrm{mL} of this solution requires 12.5 mL12.5\,\mathrm{mL} of 0.03 M KMnO40.03\,\mathrm{M}\,\mathrm{KMnO}_4 solution to reach the end point. Number of moles of Fe2+\mathrm{Fe}^{2+} present in 250 mL250\,\mathrm{mL} solution is x×10−2x \times 10^{-2} (consider complete dissolution of FeCl2\mathrm{FeCl}_2 ). The amount of iron present in the sample of y%y \% by weight.
(Assume: KMnO4\mathrm{KMnO}_4 reacts only with Fe2+\mathrm{Fe}^{2+} in the solution Use : Molar mass of iron as 56 g mol−156\,\mathrm{g}\,\mathrm{mol}^{-1} )
Section: Chemistry
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