Note: Aromatic amines (e.g. aniline) are less basic than aliphatic amines due to delocalisation of electrons. Among aliphatic amines the order of basicity in aq. solution is 2∘>1∘>3∘. The electron density is decreased in 3∘ amine due to crowding of alkyl group over N atom which makes the approach and bonding by a proton relatively difficult. Therefore the basicity decreases. ∴ The correct order of basic strength is Dimethylamine > Methyl amine > Trimethylamine > Aniline.