Secondary valency is equal to coordination number of central metal ion. In this reaction, central metal atom iron is attached with 3-oxalato ligand, and oxlaic acid it is a bidentate ligand i.e. have two donor sites. So, coordination number or secondary valency =3×2=6
FeCl3+3H2C2O4+6KOH⟶K3
[Fe(C2O4)3]
(A)
+3KCl+6H2O
Hence, product A have iron with secondary valency =6