The boiling points of amines depends upon their degree of association and the degree of association is further depends upon the extent of H-bonding. since 1∘ amines have two, 2∘ amines have one while 3∘ amines have no hydrogen atoms linked to nitrogen, therefore among isomeric amines, 1∘ amines have the highest, while 3∘ amines have the lowest boiling point. Thus, the increasing order of boiling point is