To determine the oxidation number of platinum
(Pt) in the complex ion
PtCl62−, we need to consider the oxidation numbers of the other atoms in the ion and the overall charge.
Chlorine
(Cl) is a halogen and typically has an oxidation number of -1 when it's a part of a compound but not in a neutral elemental state.
The complex ion
PtCl62− has a total charge of -2 . There are six chlorine atoms, each contributing an oxidation number of -1 . This means the total contribution of the chlorines to the charge is
6×(−1)=−6.
Now, let's set up an equation to solve for the oxidation number of platinum
(Pt), which we'll call
x: x+(6×−1)=−2Solve for
x :
x−6=−2x=−2+6x=4Thus, the oxidation number of platinum in the complex ion
PtCl62− is +4 .
The correct answer is:
Option B: +4