NCERT Class XI Chemistry Environmental Chemistry Solutions

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Question : 9
Total: 20
What are the reactions involved for ozone layer depletion in the stratosphere?
Solution:  
(i) The main reason for ozone layer depletion besides other gases are chlorofluorocarbons (CFCs).
(ii) Once CFCs are released into the atmosphere, they reach the stratosphere and release free-radicals by the action of sunlight.
CF2Cl2(g)
UV
.
Cl(g)
+
.
C
F2
C
l(g)

(iii) These radicals further react with ozone and bring about its depletion.
.
Cl(g)
+O3(g)
Cl
.
O(g)
+O2(g)

O3(g)
UV
O2(g)+O(g)
Cl
.
O(g)
+O(g)
.
Cl(g)
+O2(g)

(iv) Such regeneration of
.
Cl
radicals, causes continuous eating away of the O3 layer creating ozone holes.
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