NCERT Class XI Chemistry Structure of Atom Solutions

© examsnet.com
Question : 33
Total: 67
What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to n = 2 of He+ spectrum?
Solution:  
1
λ
=
v
= 1.097 × 107Z2[
1
n12
1
n22
]
m1

where, n1 = number of the lower energy level, n2 = number of the higher energy level, Z = atomic number, λ = wavelength,
v
= wavenumber
For He+,
1
λ
= 1.097 × 107 × (2)2[
1
(2)2
1
(4)2
]
m1

= 1.097 × 107×4(
3
16
)
= 1.097 × 107×
3
4

For H atom,
1
λ
= 1.097 × 107×(1)2×
3
4
= 1.097 × 107[
1
nL2
1
nH2
]

[
1
nL2
1
nH2
]
=
3
4
. Thig gives nL = 1 , nH = 2
The transition nL = 1 to nH = 2 in H-atom would have the same wavelength as Balmer transition n = 4 to n = 2 of He+.
© examsnet.com
Go to Question: