NCERT Class XII Chemistry
Chapter - Solutions
Questions with Solutions

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Question : 9
Total: 53
A sample of drinking water was found to be severely contaminated with chloroform,CHCl3, supposed to be a carcinogen. The level of contamination was 15 ppm (by mass):
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
Solution:  
(i) 15 ppm means 15 parts in million (10 6 ) parts by mass in the solution.
% by mass =
15
106
×100
=1.5×103

(ii) Mass of solvent =106g (Mass of solute is negligible)
Molar mass of CHCl3=12+1+3×35.5=119.5g mol1
No. of moles of CHCl3=
Massing
Molarmass
=
15
119.5

Molality =
15
119.5
106
×1000
=1.25×104 m
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