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AIEEE 2003 Chemistry Solved Paper
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© examsnet.com
Question : 58
Total: 76
Ammonia forms the complex ion
[
Cu
(
NH
3
)
4
]
2
+
with copper ions in alkaline solutions but not in acidic solutions. What is the reason for it?
In acidic solutions protons coordinate with ammonia molecules forming
NH
4
+
ions and
NH
3
molecules are not available
In alkaline solutions insoluble
Cu
(
OH
)
2
is precipitated which is soluble in excess of any alkali
Copper hydroxide is an amphoteric substance
In acidic solutions hydration protects copper ions.
Validate
Solution:
.
.
N
H
3
+
H
+
(
acidic medium
)
⇌
+
N
H
4
© examsnet.com
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