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AIEEE 2009 Solved Paper
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© examsnet.com
Question : 14
Total: 89
Two liquids
X
and
Y
form an ideal solution. At
300
K
, vapour pressure of the solution containing
1
mol
of
X
and
3
mol
of
Y
is
550
mm
Hg
. At the same temperature, if
1
mol
of
Y
is further added to this solution, vapour pressure of the solution increases by
10
mm
Hg
. Vapour pressure (in
mm
Hg
) of
X
and
Y
in their pure states will be, respectively :
200 and 300
300 and 400
400 and 600
500 and 600
Validate
Solution:
P
total
=
P
A
∘
X
A
+
P
B
∘
X
B
550
=
P
A
∘
×
1
4
+
P
B
∘
×
3
4
P
A
∘
+
3
P
B
∘
=
550
×
4
.
.
.
(
i
)
In second case
P
total
=
P
A
∘
×
1
5
+
P
B
∘
×
4
5
P
A
∘
+
4
P
B
∘
=
560
×
5
.
.
.
(
i
i
)
Subtract
(
i
)
from
(
i
i
)
∴
P
B
∘
=
560
×
5
−
550
×
4
=
600
As
P
A
∘
=
400
© examsnet.com
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