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AIEEE 2010 Solved Paper
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© examsnet.com
Question : 22
Total: 89
29.5
mg of an organic compound containing nitrogen was digested according to Kjeldahl's method and the evolved ammonia was absorbed in
20
mL
of
0.1
M
HCl
solution. The excess of the acid required
15
mL
of
0.1
M
NaOH
solution for complete neutralization. The percentage of nitrogen in the compound is
59.0
47.4
23.7
29.5
Validate
Solution:
Moles of
H
C
l
taken
=
20
×
0.1
×
10
−
3
=
2
×
10
−
3
Moles of
HCl
neutralized by
NaOH
solution
=
15
×
0.1
×
10
−
3
=
1.5
×
10
−
3
Moles of
H
C
l
neutralized by ammonia
=
2
×
10
−
3
−
1.5
×
10
−
3
=
0.5
×
10
−
3
%
of nitrogen
=
1.4
×
N
×
V
w.t. of Substance
×
100
=
1.4
×
0.5
×
10
−
3
29.5
×
10
−
3
×
100
=
23.7
%
© examsnet.com
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