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AP and TS EAMCET Engineering Model Paper 20
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© examsnet.com
Question : 122
Total: 160
At 27°C, the vapour pressure of an ideal solution containing 2 moles of A and 3 moles of B is 560 mm of Hg. If 2 moles of B is added to this solution at the same temperature, the vapour pressure of the solution increases by 40 mm of Hg. The vapour pressure of A and B are respectively are
700 mm, 350 mm
350 mm, 700 mm
600 mm, 500 mm
500 mm, 600 mm
Validate
Solution:
P
total
=
P
A
°
.
X
A
+
P
B
°
.
X
B
560
mm
=
P
A
°
.
2
2
+
3
+
P
B
°
.
3
2
+
3
∴
2
P
A
°
+
3
P
B
°
=
5
×
560
=
2800
mm
.....(1)
After adding 2 moles of B ,
600
mm
=
P
A
°
.
2
2
+
5
+
P
B
°
.
5
2
+
5
∴
2
P
A
°
+
5
P
B
°
=
7
×
600
=
4200
mm
.......(2)
(
2
)
−
(
1
)
gives
2
P
B
°
=
1400
mm
∴
P
B
°
=
700
mm
By substituting
P
B
°
in (2)
2
P
A
°
+
5
×
700
=
4200
mm
2
P
A
°
=
4200
−
3500
=
700
mm
P
A
°
=
350
mm
© examsnet.com
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