State−2 (p1,V1,T1)(p2,V2,T2) ⇒Work done in reversible compression process is smaller than the work done in irreversible compression process ⇒ ΔU=0 for reversible isothermal expansion. ΔU<0 for reversible adiabatic expansion. ⇒ For free expansion q=0,w=0 and ΔU=0 hence it is simultaneously both isothermal (ΔU=0) as well as adiabatic (q = 0). ⇒ Work done in reversible adiabatic expansion is less than the work done in reversible isothermal expansion as shown in figure