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JEE Advanced 2021 Paper 1
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© examsnet.com
Question : 14
Total: 57
Which of the following statement(s) is (are) correct about the spectrum of hydrogen atom ?
The ratio of the longest wavelength to the shortest wavelength in Balmer series is
9
∕
5
There is an overlap between the wavelength ranges of Balmer and Paschen series.
The wavelengths of Lyman series are given by
(
1
+
1
m
2
)
λ
0
, where
λ
0
is the shortest wavelength of Lyman series and
m
is an integer
The wavelength ranges of Lyman and Balmer series do not overlap
Validate
Solution:
From formula,
1
λ
=
R
[
1
n
1
2
−
1
n
2
2
]
For Balmer series,
n
1
=
2
∴
For longest wavelength, transition occurs from
n
=
3
to
n
=
2
.
∴
1
λ
max
=
R
[
1
2
2
−
1
3
2
]
for shortest wavelength transition occurs from
n
=
∞
to
n
=
2
∴
1
λ
min
=
R
[
1
2
2
−
1
∞
2
]
∴
λ
longest
λ
shorts
=
9
5
For Paschen series,
n
1
=
3
λ
longest
of Balmer
=
36
5
R
and
λ
shortest
of Paschen
=
9
R
Hence there is no overlap between the wavelength ranges of Balamer and Paschen series.
For Lyman series,
n
1
=
1
1
λ
=
R
[
1
1
−
1
m
2
]
Also
1
λ
0
=
R
∴
1
λ
=
1
λ
0
[
1
−
1
m
2
]
⇒
λ
=
λ
0
1
−
1
m
2
λ
longest
of Lyman
=
4
3
R
and
λ
shortest
of Balmer
=
4
R
Hence that wavelenght ranges of Lyman and Balmer series do not overlap.
© examsnet.com
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