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JEE Advanced Model Paper 14 with solutions for online practice
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© examsnet.com
Question : 24
Total: 60
For the cell representation Ag (s) | AgBr (s) | KBr (aq)
C
1
|| KCl (s) | Ag (s) ; which of the following facts are true?
P : It is an example of concentration cell, if the concentration of metal ion used in both the half cells is identical
Q: This cell can also be represented as Ag |
A
g
(
(
K
s
p
)
A
g
B
r
B
r
−
)
+
||
A
g
(
(
K
s
p
)
A
g
C
l
C
l
−
)
+
| Ag
R: It is an example of electrolytic concentration cell
S: The cell reaction would be spontaneous if
(
K
s
p
)
A
g
B
r
×
[
C
l
−
]
<
(
K
s
p
)
A
g
C
r
×
[
B
r
−
]
P
R
QS
PQRS
Validate
Solution:
Given cell consists of half cells of metal - metal insoluble salt. Each can be reduced to metal - metal ion half cell
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