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JEE Main Chemistry Class 12 Co-ordination Compounds Part 3 Questions
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Question : 40
Total: 82
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A
: The spin only magnetic moment value for
[
Fe
(
CN
)
6
]
3
−
is
1.74
BM
, whereas for
[
Fe
(
H
2
O
)
6
]
3
+
is
5.92
BM
.
Reason
R
: In both complexes,
Fe
is present in +3 oxidation state.
In the light of the above statements, choose the correct answer from the options given below:
[6-Apr-2023 shift 1]
Both A and R are true but R is NOT the correct explanation of
A
A is false but R is true
A is true but
R
is false
Both A and R are true and R is the correct explanation of
A
Validate
Solution:
[
Fe
(
CN
)
6
]
3
−
Unpaired electron
=
1
µ
=
√
n
(
n
+
2
)
=
√
1
×
3
=
1.74
B.M.
[
Fe
(
H
2
O
)
6
]
3
+
No pairing because
H
2
O
is WFL
Number of unpaired electrons
=
5
,
µ
=
5.92
BM
Assertion is true, Reason is true but not correct explanation.
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