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JEE Main Chemistry Class 11 Equilibrium Questions Part 2 Questions

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Question : 45

Total: 100

A solution is 0.1M in Cl−and 0.001M in CrO42−.
Solid AgNO3 is gradually added to it Assuming that the addition does not change in volume and Ksp (AgCl)=1.7×10−10M2 andKsp(Ag2CrO4)=1.9×10−12M3
Select correct statement from the following:

[20 Jul 2021 Shift 2]

AgCl precipitates first because its Ksp is high.
Ag2CrO4 precipitates first as its Ksp is low.
Ag2CrO4 precipitates first because the amount of Ag+needed is low.
AgCl will precipitate first as the amount of Ag+ needed to precipitate is low.

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