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JEE Main Chemistry Class 11 Equilibrium Questions Part 2 Questions
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Question : 88
Total: 100
For the following Assertion and Reason, the correct option is
[Sep. 02,2020(I)]
Assertion (A):
When Cu (II) and sulphide ions are mixed, they react together extremely quickly to give a solid.
Reason (R):
The equilibrium constant of
C
u
2
+
(
a
q
)
+
S
2
−
(aq)
⇌
C
u
S
(
s
)
is high because the solubility product is low.
(A) is false and (R) is true
Both (A) and (R) are false
Both (A) and (R) are true but (R) is not the explanation for
(
A
)
Both (A) and (R) are true and (R) is the explanation for (A)
Validate
Solution:
C
u
2
+
ions get precipitated every quickely due to low
K
s
p
value even at very low concentration of
S
2
−
ion.
C
u
S
(
s
)
⇌
C
u
2
+
+
S
2
−
K
s
p
=
[
C
u
2
+
]
[
S
2
−
]
C
u
2
+
+
S
2
−
⇌
C
u
S
(
s
)
K
e
q
=
1
[
C
u
2
+
]
[
S
2
−
]
=
1
K
s
p
Due to high value of
K
eq
, CuS precipitated easily.
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